Related Experiment Video
Updated: Jun 24, 2026
06:48
Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
Published on: June 14, 2024
Incorporation of Fe3O4 nanoparticles into organometallic coordination polymers by nanoparticle surface modification
Sang Bok Kim1, Chen Cai, Shouheng Sun
1Department of Chemistry, Brown University, Providence, RI 02912, USA.
Angewandte Chemie (International Ed. in English)
|March 17, 2009
Abstract:
Surface-modified Fe(3)O(4) nanoparticles (NPs) can be obtained by substituting [(eta(5)-semiquinone)Mn(CO)(3)] for oleylamine surface protecting groups. The resulting NP can function as a nucleus or template to generate crystalline coordination polymers that contain superparamagnetic Fe(3)O(4) NPs. Hybridized magnetic properties can be obtained by introducing paramagnetic metal nodes, such as Mn(2+), into the polymers (see picture).
