Unintended parametric ejection of ions from an ion cyclotron resonance trap by two- electrode axialization

Azimuthal quadrupolar excitation is a commonly used technique in the field of ion cyclotron resonance mass spectrometry, in particular in combination with buffer-gas collisions to achieve axialization of the stored ions. If the quadrupolar excitation is applied with only one phase to a set of two opposing ring segments (rather than the "regular" method where two sets of electrodes are addressed with opposite polarities), parametric resonance effects at the frequencies 2nu(z) and nu(p) = nu(+) - nu(-) can lead to unintended ejection of ions from the trap. These parametric resonances have been revisited both theoretically and experimentally: multipole components of different azimuthal excitation schemes are derived by a simple vector representation of the excitation signal applied to the ring segments. Thus, parametric contributions can be easily identified, as demonstrated for the two-electrode and the four-electrode quadrupolar excitation schemes as well as further examples. In addition, the effect of the single-phase two-electrode quadrupolar excitation is demonstrated for storage and axialization of cluster ions.