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Polymerization of phenylacetylene by rhodium complexes within a discrete space of apo-ferritin

Satoshi Abe1, Kunio Hirata, Takafumi Ueno

  • 1Institute for Integrated Cell-Material Sciences, Funai Center, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.

Journal of the American Chemical Society
|May 21, 2009
PubMed

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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...