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Bulk and Thin Film Synthesis of Compositionally Variant Entropy-stabilized Oxides
Published on: May 29, 2018
Optical functions of (x)GeO2:(1-x)SiO2 films determined by multi-sample and multi-angle spectroscopic ellipsometry
Optics Express
|June 5, 2009
Summary
This study fabricates germanium dioxide-silicon dioxide (GeO2:SiO2) thin films using sol-gel methods. Spectroscopic ellipsometry reveals their optical properties, enabling prediction of refractive indices for optics and photonics applications.
Area of Science:
- Materials Science
- Optics and Photonics
- Ceramic Engineering
Background:
- Germanium dioxide-silicon dioxide (GeO2:SiO2) is a key binary ceramic material.
- Understanding its optical dispersion is crucial for optics and photonics.
- Sol-gel fabrication offers a versatile route for thin film synthesis.
Purpose of the Study:
- To fabricate GeO2:SiO2 thin films with varying compositions (0 ≤ x ≤ 0.4).
- To accurately determine the optical dispersion relationship of these films.
- To develop a predictive model for refractive indices based on composition.
Main Methods:
- Sol-gel technique for thin film fabrication.
- Spectroscopic ellipsometry (SE) using multi-sample and multi-angle measurements.
- Sellmeier model application for optical dispersion analysis.
Main Results:
- Homogeneous and amorphous GeO2:SiO2 films were successfully produced.
- A reliable method for creating a dispersion-composition surface was established.
- Optical dispersion properties were characterized from 210 to 1700 nm.
- Composition-dependent dispersion parameters, material dispersion coefficient, and zero-dispersion wavelength were quantified.
Conclusions:
- The Sellmeier model accurately describes the optical dispersion of GeO2:SiO2 films.
- The developed method allows for visualization and prediction of refractive indices.
- Composition significantly influences the optical dispersion characteristics of these films.
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