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Related Concept Videos

X-ray Crystallography02:18

X-ray Crystallography

The size of the unit cell and the arrangement of atoms in a crystal may be determined from measurements of the diffraction of X-rays by the crystal, termed X-ray crystallography.
Diffraction
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In the late 1800s, the revelation that light extended beyond visible wavelengths led to the discovery of X-rays by Wilhelm Roentgen. Recognized as high-energy electromagnetic radiation with short wavelengths, X-rays prompted exploration into their interaction with crystals. Max von Laue proposed in 1912 that the periodic arrangement of atoms, ions, or molecules in crystals would cause them to diffract X-rays, a hypothesis confirmed through experiments with copper sulfate and zinc sulfide...
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X-ray diffraction or XRD is an analytical tool that utilizes X-rays to study ordered structures such as crystalline organic and inorganic samples, polycrystalline materials, proteins, carbohydrates, and drugs.
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Measurements of Long-range Electronic Correlations During Femtosecond Diffraction Experiments Performed on Nanocrystals of Buckminsterfullerene
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Time-resolved electron diffraction from selectively aligned molecules.

Peter Reckenthaeler1, Martin Centurion, Werner Fuss

  • 1Max-Planck-Institut für Quantenoptik, Hans-Kopfermann-Strasse 1, D-85748 Garching, Germany.

Physical Review Letters
|June 13, 2009
PubMed
Summary
This summary is machine-generated.

Researchers achieved ultrafast electron diffraction from molecules aligned without external fields. This alignment, created by laser pulses, decayed within picoseconds, offering a new method for studying molecular dynamics.

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Area of Science:

  • Molecular dynamics
  • Ultrafast electron diffraction
  • Femtosecond spectroscopy

Background:

  • Studying transient molecular alignment is crucial for understanding chemical reactions.
  • External fields are typically used to align molecules, but this can interfere with measurements.
  • Developing field-free alignment methods is essential for accurate probing of molecular motion.

Purpose of the Study:

  • To experimentally demonstrate ultrafast electron diffraction from molecules aligned without external fields.
  • To investigate the dynamics of field-free molecular alignment.
  • To establish a novel technique for probing molecular structure and dynamics.

Main Methods:

  • Generating molecular alignment via femtosecond laser pulse photodissociation.
  • Probing the aligned molecules using picosecond electron pulses.
  • Measuring ultrafast electron diffraction patterns.

Main Results:

  • Successfully demonstrated ultrafast electron diffraction from transiently aligned molecules.
  • Observed that molecular alignment decays with a time constant of 2.6 ± 1.2 picoseconds.
  • Showcased the feasibility of field-free alignment for diffraction studies.

Conclusions:

  • Field-free molecular alignment can be effectively generated and utilized for ultrafast electron diffraction.
  • The rapid decay of alignment (picosecond timescale) necessitates prompt probing.
  • This technique offers a promising avenue for investigating ultrafast molecular dynamics.