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Updated: Jun 21, 2026

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Colloidal silicon nanorod synthesis.

Andrew T Heitsch1, Colin M Hessel, Vahid A Akhavan

  • 1Department of Chemical Engineering, Texas Materials Institute, and Center for Nano- and Molecular Science and Technology, The University of Texas at Austin, Texas 78712-1062, USA.

Nano Letters
|July 16, 2009
PubMed
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Colloidal synthesis yields crystalline silicon nanorods using trisilane and gold nanocrystals. Dodecylamine stabilizes these nanorods, with post-synthesis etching removing gold seeds.

Area of Science:

  • Materials Science
  • Nanotechnology
  • Colloidal Chemistry

Background:

  • Silicon nanostructures are crucial for advanced electronics and photonics.
  • Controlled synthesis of silicon nanorods with specific dimensions remains a challenge.

Purpose of the Study:

  • To demonstrate a colloidal synthesis method for crystalline silicon (Si) nanorods.
  • To control nanorod dimensions and surface properties.

Main Methods:

  • Colloidal synthesis involving the decomposition of trisilane in a hot solvent.
  • Utilizing gold (Au) nanocrystals as seeds for solution-liquid-solid growth.
  • Employing dodecylamine as capping ligands for stabilization.

Main Results:

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Last Updated: Jun 21, 2026

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  • Successfully synthesized crystalline silicon nanorods with diameters of 5-10 nm and lengths of 15-75 nm.
  • Demonstrated Au-seeded solution-liquid-solid growth mechanism.
  • Showcased post-synthesis etching of Au seeds from nanorod tips.
  • Conclusions:

    • The described colloidal method enables controlled synthesis of Si nanorods.
    • Dodecylamine effectively stabilizes the nanorod dispersion.
    • The process allows for the removal of Au seeds, yielding pure Si nanorods.