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Innermolecular reactions of fluorophenylcarbene inside a hemicarcerand

Zhifeng Lu1, Robert A Moss, Ronald R Sauers

  • 1Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, USA.

Organic Letters
|August 7, 2009
PubMed
Summary

Photolysis of fluorophenyldiazirine within a hemicarcerand host creates a reactive fluorophenylcarbene. This carbene modifies the host molecule, forming a novel derivative, but is unstable above 100 K.

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