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Related Concept Videos

Atomic Absorption Spectroscopy: Instrumentation01:22

Atomic Absorption Spectroscopy: Instrumentation

An atomic absorption spectrophotometer (AAS) comprises several components: a radiation source, an atomizer, a monochromator, and a detector. The radiation source can be a hollow-cathode lamp (HCL) or an electrodeless-discharge lamp (EDL), both of which provide a narrow emission line of the required wavelength. However, some instruments use continuum sources and high-resolution monochromators to achieve a narrow range of radiation.
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Atomic absorption spectroscopy (AAS) relies on the Beer-Lambert law, which requires that the radiation source emits a narrow range of wavelengths to match the absorption characteristics of the analyte atom. The primary criteria for choosing an appropriate radiation source in AAS is to provide a precise and intense emission at specific wavelengths that will allow accurate detection of the analyte.
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Related Experiment Video

Updated: Jun 20, 2026

In Situ Measurement of Vacuum Window Birefringence using 25Mg+ Fluorescence
07:03

In Situ Measurement of Vacuum Window Birefringence using 25Mg+ Fluorescence

Published on: June 13, 2020

Pair-absorption-pumped barium laser.

R W Falcone1, G A Zdasiuk

  • 1Edward L. Ginzton Laboratory, Stanford University, Stanford, California 94305, USA.

Optics Letters
|August 21, 2009
PubMed
Summary
This summary is machine-generated.

This study demonstrates pair-absorption transitions for optically pumping lasers for the first time. Researchers achieved laser emission using simultaneous excitation of colliding barium and thallium atoms.

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Area of Science:

  • Atomic physics
  • Laser science

Background:

  • Optically pumping lasers typically involves single-atom transitions.
  • Pair-absorption transitions offer a novel excitation pathway.

Purpose of the Study:

  • To demonstrate the feasibility of using pair-absorption transitions for optical pumping of lasers.
  • To achieve laser emission via simultaneous excitation of colliding atoms.

Main Methods:

  • Utilized a mixture of barium and thallium metal vapors.
  • Employed single-photon absorption at 3867 Å to excite colliding ground-state atoms.
  • Observed laser emission on a specific barium atomic transition.

Main Results:

  • Achieved simultaneous excitation of barium and thallium atoms to specific excited states.
  • Created high excited-state densities (approximately 10^14 cm^-3).
  • Observed laser emission at 1.5 micrometers on the Ba(6s6p 1PI(o)) - Ba(6s5d 1D2) transition.

Conclusions:

  • Pair-absorption transitions are a viable method for optically pumping lasers.
  • This technique enables efficient creation of excited-state populations for laser operation.