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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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A 3D open-framework indium telluride and its selenide and sulfide analogues

Cheng Wang1, Xianhui Bu, Nanfeng Zheng

  • 1Department of Chemistry, University of California, Riverside, CA 92521, USA.

Angewandte Chemie (International Ed. in English)
|September 16, 2009
PubMed
Abstract

No abstract available in PubMed .

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.

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