Related Experiment Video
Updated: Jun 19, 2026

Reverse Microemulsion-mediated Synthesis of Monometallic and Bimetallic Early Transition Metal Carbide and Nitride Nanoparticles
Published on: November 27, 2015
Facile route to nitrides: transformation from single element to binary and ternary nitrides at moderate temperature
Bo Song1, Xiaolong Chen, Jiecai Han
1The Research Station on Material Science and Engineering for Postdoctoral Fellows, Harbin Institute of Technology,Harbin 150080, China. songbo@hit.edu.cn
Abstract:
In this article, we report a new modified solid-state metathesis pathway to synthesize nitrides using Li(3)N as a nitrification reagent to transform single element to nitrides. In this process, not only binary (including mono- and multinitrides) but also ternary nitrides can be approached by varying the molar ratio of Li(3)N to a single element. A possible two-step reaction mechanism for Li(3)N and single elements was proposed. This study provides a promising route to meet the increasing demand in energy savings and environmental protection for materials synthesis.
More Related Videos
Related Concept Videos
Preparation of Nitriles
Nitriles to Ketones: Grignard Reaction
The mechanism begins with a nucleophilic attack by the Grignard reagent...
Preparation of Amines: Reduction of Amides and Nitriles
Amides can be reduced to primary, secondary, and tertiary amines using catalytic hydrogenation, active metals like Fe,...
Reduction of Alkynes to trans-Alkenes: Sodium in Liquid Ammonia
When dissolved in liquid ammonia, an alkali metal, such as sodium, dissociates into a...
1° Amines to Diazonium or Aryldiazonium Salts: Diazotization with NaNO2 Mechanism
Nuclear Transmutation

