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Updated: Jun 19, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
Published on: February 11, 2012
Synthesis and characterization of a germanium bismethanediide complex
Cechao Foo1, Kai-Chung Lau, Yi-Fan Yang
1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371.
Abstract:
The reaction of [(PPh(2)=S)(2)CH(2)] (1) with MeLi followed by a salt elimination reaction with GeCl(4) in toluene afforded a novel germanium bismethanediide complex, 2. The structure of compound 2 has been determined by X-ray crystallography. The topological analysis of the electron densities of compound 2 was performed.
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