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Melamine-bridged bis(porphyrin-Zn(II)) receptors: molecular recognition properties

Tommaso Carofiglio1, Elisa Lubian, Ileana Menegazzo

  • 1Department of Chemical Sciences and ITM-CNR, University of Padua, Padua, Italy. tommaso.carofiglio@unipd.it

The Journal of Organic Chemistry
|November 6, 2009
PubMed

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Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
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