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Related Concept Videos

Molecular Weight of Step-Growth Polymers01:08

Molecular Weight of Step-Growth Polymers

Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...

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Related Experiment Video

Updated: Jun 16, 2026

Fabrication of Refractive-index-matched Devices for Biomedical Microfluidics
09:54

Fabrication of Refractive-index-matched Devices for Biomedical Microfluidics

Published on: September 10, 2018

Low-loss polymer films with adjustable refractive index.

V Ramaswamy, H P Weber

    Applied Optics
    |February 4, 2010
    PubMed
    Summary

    Researchers created polymer films with tunable refractive indices by blending polymethyl methacrylate (PMMA) and styrene-acrylonitrile copolymer (SAN). This method offers a simple way to control optical properties for potential applications.

    Area of Science:

    • Materials Science
    • Polymer Science
    • Optoelectronics

    Background:

    • Developing materials with tunable optical properties is crucial for advanced photonic devices.
    • Polymethyl methacrylate (PMMA) and styrene-acrylonitrile copolymer (SAN) are common polymers with distinct optical characteristics.

    Purpose of the Study:

    • To create solution-deposited polymer films with continuously adjustable refractive indices.
    • To investigate the compatibility and optical properties of PMMA/SAN blends.

    Main Methods:

    • Blending polymethyl methacrylate (PMMA) and styrene-acrylonitrile copolymer (SAN) in solution.
    • Fabricating thin polymer films via solution deposition.
    • Measuring the refractive index and optical losses of the films.

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    Main Results:

    • Achieved continuously adjustable refractive indices ranging from 1.489 to 1.563.
    • Observed a linear relationship between refractive index and polymer composition, indicating good miscibility.
    • Measured low optical losses (<0.2 dB/cm) in ~2 micrometer thick films.
    • Noted increased scattering losses in thicker (3.5 micrometer) films with high SAN content.

    Conclusions:

    • PMMA and SAN are miscible and can be blended to create polymer films with tunable refractive indices.
    • Solution processing offers a viable method for fabricating optical films with controlled properties.
    • Film thickness and composition influence optical loss, with implications for device design.