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Related Concept Videos

IR Spectrometers01:25

IR Spectrometers

There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...
Infrared (IR) Spectroscopy: Overview01:09

Infrared (IR) Spectroscopy: Overview

When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation corresponding to the energy difference between the two states. The absorption of infrared (IR) radiation causes transitions between vibrational energy levels in a molecule. Therefore, IR spectroscopy is a useful analytical tool for determining the molecular structure of molecules.
Different compounds display unique properties due to their...
UV–Vis Spectrometers01:14

UV–Vis Spectrometers

The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell. Samples for...
Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy  (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used.
Raman Spectroscopy Instrumentation: Overview01:26

Raman Spectroscopy Instrumentation: Overview

A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview01:13

Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview

Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely employed in chemistry, materials science, forensic science, and other fields where sample characterization is required. ATR has several advantages over traditional transmission IR spectroscopy, including the requirement of little to no sample preparation and the ability to analyze a wide range of samples.
The ATR process begins by directing a beam...

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Updated: Jun 16, 2026

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing
10:42

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Multiplexed dispersive spectrometers using reduced background infrared detectors.

C L Wyatt, R W Esplin

    Applied Optics
    |February 6, 2010
    PubMed
    Summary

    Multiplex spectrometry for cooled photodetectors is hindered by system noise, limiting throughput. Doubly encoded systems offer potential throughput gains proportional to matrix elements, overcoming bandwidth limitations.

    Area of Science:

    • Optics and Photonics
    • Infrared Technology
    • Detector Physics

    Background:

    • Multiplex spectrometry is applied to cryogenically cooled Long-Wave Infrared (LWIR) extrinsic photodetectors.
    • System noise is a primary limitation in these applications.
    • Detector Noise Equivalent Power (NEP) is directly proportional to bandwidth.

    Purpose of the Study:

    • To investigate the limitations of multiplex spectrometry in LWIR photodetectors.
    • To explore alternative multiplexing schemes for improved performance.
    • To identify strategies for enhancing detector throughput.

    Main Methods:

    • Analysis of noise limitations in multiplexed photodetector systems.
    • Evaluation of bandwidth dependency of detector NEP.

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  • Theoretical assessment of doubly encoded multiplexing strategies (2n - 1 and n + N - 1 measurements).
  • Main Results:

    • Increased bandwidth in multiplex schemes does not yield significant advantages due to noise limitations.
    • Doubly encoded systems demonstrate potential for real throughput gain.
    • Throughput gain is proportional to the number of elements in the throughput matrix.

    Conclusions:

    • System noise fundamentally limits multiplex spectrometry for cooled LWIR photodetectors.
    • Doubly encoded multiplexing offers a viable path to increase detector throughput.
    • Future research should focus on doubly encoded systems to overcome bandwidth constraints.