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Updated: Jun 16, 2026
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Molecular tectonics: formation and structural studies on a 2-D directional coordination network based on a
Jérôme Ehrhart1, Jean-Marc Planeix, Nathalie Kyritsakas-Gruber
1Laboratoire de Chimie de Coordination Organique (UMR CNRS 7140), Université de Strasbourg, Institut Le Bel, 4 rue Blaise Pascal, 67000 Strasbourg, France.
Abstract:
The combination of tectons based on the [1111]metacyclophane backbone blocked the 1,3-alternate conformation bearing two imidazoly or pyrazolyl groups located on the same side with metal halide complexes leads to the formation of either discrete metallmacrobicycles or infinite 1-D coordination networks. The same backbone bearing two sets of two different coordinating poles composed of two pyridyl and two pyrazolyl units, owing to its non-centrosymmetric nature, forms a directional 2-D network packed in an anti-parallel fashion.
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