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Synthesis of the anti-virus compound shuangkangsu's analogs
Di-Zao Li1, Yan-Bo Tang, Zhi-Yun Kang
1The Key Laboratory of Bioactive Substances and Resources Utilization of Chinese Herbal Medicine, Peking Union Medical College, Ministry of Education, Beijing, China.
Journal of Asian Natural Products Research
|February 26, 2010
Abstract:
Four novel cyclic peroxide glucosides 15a, 15b, 16a, and 16b, optically pure analogs of shuangkangsu (1), which is an anti-virus natural product with an unusual skeleton isolated from the buds of Lonicera japonica Thunb, were first synthesized totally in six steps including cycloaddition of furan with diethyl acetylenedicarboxylate and glycosylation.
