Related Experiment Video
Updated: Jun 15, 2026

In Situ Monitoring of Diffusion of Guest Molecules in Porous Media Using Electron Paramagnetic Resonance Imaging
Published on: September 2, 2016
Measurement of vorticity diffusion by NMR microscopy
Jennifer R Brown1, Paul T Callaghan
1Victoria University of Wellington, School of Chemical and Physical Sciences, The MacDiarmid Institute of Advanced Materials and Nanotechnology, PO Box 600, Wellington 6012, New Zealand. jbrown@coe.montana.edu
Researchers measured kinematic viscosity in low-viscosity fluids by imaging vorticity diffusion using rapid Nuclear Magnetic Resonance (NMR) velocimetry. This technique avoids direct stress measurements, offering a novel approach for fluid characterization.
Area of Science:
- Fluid dynamics
- Rheology
- Nuclear Magnetic Resonance (NMR) spectroscopy
Background:
- Vorticity diffusion in Newtonian fluids is governed by kinematic viscosity.
- Accurate measurement of kinematic viscosity is crucial for understanding fluid behavior.
- Traditional methods for viscosity measurement can be complex or require stress measurement.
Purpose of the Study:
- To develop and validate a novel method for measuring kinematic viscosity.
- To investigate the diffusion of vorticity in a fluid-filled cylinder during startup.
- To demonstrate the utility of rapid NMR velocimetry for fluid property determination.
Main Methods:
- Utilized rapid Nuclear Magnetic Resonance (NMR) velocimetry, employing a RARE sequence.
- Imaged the time-dependent velocity field within a fluid-filled cylinder.
- Initiated fluid motion by rotating the cylinder's outer wall to a fixed angular velocity.
Main Results:
- Successfully imaged the diffusion of vorticity.
- Experimental results align with the theoretical solution of the vorticity diffusion equation.
- Demonstrated a method to determine kinematic viscosity without direct stress measurement.
Conclusions:
- Rapid NMR velocimetry provides an effective means to measure kinematic viscosity.
- The technique is particularly suitable for low-viscosity fluids.
- This study offers a non-invasive approach for fluid characterization.
Related Concept Videos
NMR Spectroscopy: Spin–Spin Coupling
2D NMR: Overview of Heteronuclear Correlation Techniques
Two-Dimensional (2D) NMR: Overview
The first step is the preparation period, during which nucleus A is excited with a radiofrequency pulse.
¹H NMR: Interpreting Distorted and Overlapping Signals
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are slanted or...
2D NMR: Overview of Homonuclear Correlation Techniques
COSY90 is the standard two-dimensional (2D) COSY experiment that...
Applications Of NMR In Biology
The...

