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Asymmetric total synthesis of the caspase-1 inhibitor (-)-berkeleyamide A

Swapnil J Kulkarni1, Yakambram Pedduri, Amar G Chittiboyina

  • 1Department of Medicinal Chemistry, School of Pharmacy, The University of Mississippi, University, Mississippi 38677, USA.

The Journal of Organic Chemistry
|April 2, 2010
PubMed

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Caspases01:24

Caspases

Caspase, a family of cysteine proteases, serve as effectors in apoptosis. The ced3 gene in C.elegans was first identified to be involved in apoptosis. This gene encodes the ced-3 caspase that is similar to the interleukin-1-beta converting enzyme or ICE in mammals. In addition to apoptosis, caspases also function in the inflammatory response. Inflammatory caspases are essential in activating pro-inflammatory cytokines that recruit immune cells and block the replication of pathogens inside cells.