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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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Large angular jump mechanism observed for hydrogen bond exchange in aqueous perchlorate solution

Minbiao Ji1, Michael Odelius, K J Gaffney

  • 1PULSE Institute for Ultrafast Energy Science, SLAC National Accelerator Laboratory, Stanford University, Stanford, CA 94305, USA.

Science (New York, N.Y.)
|May 22, 2010
PubMed
Summary

Water molecules switch hydrogen bonds through large, prompt angular rotations in aqueous solutions. This study quanties the average jump angle, providing new insights into hydrogen bond dynamics.

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