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Isolation and Compositional Analysis of Plant Cuticle Lipid Polyester Monomers
Published on: November 22, 2015
Gallic acid esters from the stem bark of Mimusops elengi L
Nida Akhtar1, Mohd Ali, Mohd Sarwar Alam
1Department of Chemistry, Faculty of Science, Jamia Hamdard (Hamdard University), New Delhi-110 062, India.
Abstract:
Phytochemical investigation of the ethanolic extract of the stem bark of Mimusops elengi L. (Sapotaceae) led to the isolation of new gallic acid esters, characterised as phenyl propanoxyl gallate (1), beta-D-glucopyranosyl (6'-->1'')-beta-D-glucopyranosyl-4''-(4''-ethylphenyl) gallate (2), 2'-(1'''-geranyloxy)-beta-D-glucopyranosyl (6'-->1'')-beta-D-glucopyranosyl-4''-phenoxy gallate (3), beta-D-glucopyranosyl (6'-->1'')-beta-D-glucopyranosyl 3,4,5-trihydroxy benzoate (4), beta-D-glucopyranosyl-(6'-->1'')-beta-D-glucopyranosyl-4''-(4'''-n-butylphenyl) 3,4,5-trihydroxy benzoate (5), beta-D-glucopyranosyl(6'-->1'')-beta-D-rhamnosyl 3,4,5-trihydroxy benzoate (6) and beta-D-(2'-phenyl glucopyranosyl)-(6'-->1'')-(2'', 4''-diphenylrhamnopyranosyl)-3,4,5-trihydroxylbenzoate (7), along with the known compounds: farnon-3-one, stigmasta-5-en-3-beta-ol, olean-18-en-2-one-3-ol, lup-20(29)-en-3beta-ol and stigmasta-5-en-3beta-D-glucopyranoside. Their structures were elucidated on the basis of spectroscopic analyses and chemical reactions.
