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Updated: Jun 10, 2026

Synthesis of Core-shell Lanthanide-doped Upconversion Nanocrystals for Cellular Applications
Published on: November 10, 2017
Poly (acrylic acid)-capped lanthanide-doped BaFCl nanocrystals: synthesis and optical properties
Qiang Ju1, Wenqin Luo, Yongsheng Liu
1Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Abstract:
Water-soluble lanthanide-doped BaFCl nanophosphors with the surface functionalized by a layer of poly (acrylic acid) are synthesized via a facile one-step solvothermal method. Intense long-lived luminescence is realized from visible to near-infrared (NIR) by doping with different lanthanide ions. The emission and excitation spectra of Eu(3+) indicate that the doped lanthanide ions occupy a site close to the surface of the nanoparticles. Strong NIR emissions of Nd(3+) and green luminescence of Tb(3+) using Ce(3+) as sensitizers are also achieved in BaFCl nanoparticles. The synthesized nanoparticles featuring long-lived luminescence in either visible or NIR regions may have potential applications as luminescent labels for biological applications.

