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Updated: Jun 9, 2026

Fabrication, Densification, and Replica Molding of 3D Carbon Nanotube Microstructures
Published on: July 2, 2012
Fabrication of highly conductive and transparent thin films from single-walled carbon nanotubes using a new non-ionic
Jea Woong Jo1, Jae Woong Jung, Jea Uk Lee
1WCU Hybrid Materials Program, Department of Materials Science and Engineering, Seoul National University, Seoul 151-742, Korea.
Abstract:
Oligothiophene-terminated poly(ethylene glycol) was synthesized and used as a non-ionic and amphiphilic surfactant for fabricating high-quality single-walled carbon nanotube (SWCNT) films by a simple spin coating method. The absence of charge repulsion between SWCNT/surfactant complexes successfully leads to formation of a dense network of SWCNTs on the substrate through a single deposition of spin coating. When the SWCNT film was treated with nitric acid and thionyl chloride after washed with dichloromethane and water, a high-performance SWCNT film with the sheet resistance of 59 ohm/sq and the transparency of 71% at 550 nm was successfully obtained. Since the SWCNT film exhibits a high value of σ(dc)/σ(ac) (∼17) and excellent dimensional stability after releasing from the substrate, the film can be used as a transparent electrode in flexible optoelectronic devices.

