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Synthesis of a Water-soluble Metal–Organic Complex Array
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Practical approach to structurally diverse monoimine salts and nonsymmetrical metallosalphen complexes

Eduardo C Escudero-Adán1, Marta Martínez Belmonte, Jordi Benet-Buchholz

  • 1Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.

Organic Letters
|September 18, 2010
PubMed
Summary

Researchers developed a straightforward method to synthesize monoimine NBu(4) salts from Zn(salphen) complexes. This technique utilizes nucleophilic addition and hydrolysis, yielding versatile reagents for creating tunable metallosalens.

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