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Updated: Jun 8, 2026

Measuring Magnetically-Tuned Ferroelectric Polarization in Liquid Crystals
Published on: August 15, 2018
Interplay between charge order, ferroelectricity, and ferroelasticity: tungsten bronze structures as a playground for
Kunihiko Yamauchi1, Silvia Picozzi
1Consiglio Nazionale delle Ricerche (CNR-SPIN), 67100 L'Aquila, Italy.
None:
Charge order is proposed as a driving force behind ferroelectricity in iron fluoride K(0.6)Fe(0.6)(II)Fe(0.4)(III)F(3). By means of density functional theory, we propose several noncentrosymmetric d(5)/d(6) charge-ordering patterns, each giving rise to polarization with different direction and magnitude. Accordingly, we introduce the concept of "ferroelectric anisotropy" (peculiar to improper ferroelectrics with polarization induced by electronic degrees of freedom), denoting the small energy difference between competing charge-ordered states. Moreover, we suggest a novel type of charge-order-induced ferroelasticity: a monoclinic distortion is induced by a specific charge-ordering pattern, which, in turn, determines the direction of polarization. K(0.6)Fe(0.6)(II)Fe(0.4)(III)F(3) therefore emerges as a prototypical compound, in which the intimately coupled electronic and structural degrees of freedom result in a peculiar multiferroicity.
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