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Updated: Jun 8, 2026

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Algebraic displacement correlation in two-dimensional polymer melts
J P Wittmer1, H Meyer, A Johner
1Institut Charles Sadron, 23 rue du Loess, BP 84047, 67034 Strasbourg Cedex 2, France. joachim.wittmer@ics-cnrs.unistra.fr
Abstract:
Dense self-avoiding polymer chains in strictly two dimensions are compact objects with fractal contours. Using scaling arguments and molecular dynamics simulations (with negligible momentum conservation) it is shown that correlated amoebalike fluctuations of the (sub)chain contours dominate the relaxation dynamics on all scales. The incompressibility of the melt and the compactness of (sub)chains impose a scale-free constraint on the contour fluctuations. This leads to strong long range spatiotemporal correlations of the displacement field as shown, e.g., by the (negative) algebraic decay of the center-of-mass velocity correlation function C(t)∼-1/t(6/5) with time t.
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