Related Experiment Video
Updated: Jun 8, 2026

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)
Published on: January 17, 2020
Methoxy species on Cu(110): understanding the local structure of a key catalytic reaction intermediate
M K Bradley1, D Kreikemeyer Lorenzo, W Unterberger
1Physics Dept, University of Warwick, Coventry CV4 7AL, United Kingdom.
Abstract:
Partial oxidation of methanol to formaldehyde over Cu(110) is one of the most studied catalytic reactions in surface science, yet the local site of the reaction intermediate, methoxy, remains unknown. Using a combination of experimental scanned-energy mode photoelectron diffraction, and density functional theory, a consistent structural solution is presented in which all methoxy species occupy twofold coordinated "short-bridge" adsorption sites. The results are consistent with previously-published scanning tunnelling microscopy images and theoretical calculations of the reaction mechanism.
More Related Videos
10:19Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
Published on: July 18, 2017
10:52Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics
Published on: April 12, 2019
Related Concept Videos
Catalysis
Heterogeneous Catalysis
Alkenes via Reductive Coupling of Aldehydes or Ketones: McMurry Reaction
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide