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Dynamics of highly excited nitroaromatics.

Bingxing Wang1, Benkang Liu, Yanqiu Wang

  • 1State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Dalian 116023, China.

The Journal of Physical Chemistry. A
|November 25, 2010
PubMed
Summary

Highly excited nitroaromatics undergo ultrafast deactivation via internal conversion to Rydberg and ground states. Methyl substitution accelerates this process, with an ortho effect in o-nitrotoluene significantly enhancing the speed of nitroaromatic fragmentation.

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