Exploring the reactions of CO2 with PCP supported nickel complexes
Timothy J Schmeier1, Nilay Hazari, Christopher D Incarvito
1The Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut 06520, USA.
Abstract:
The reactions of PCP supported Ni hydride, methyl and allyl species with CO(2) to generate Ni carboxylates are described. Computational studies suggest that all three reactions follow different pathways.
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