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Updated: Jun 5, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Bis[(2-quinol-yl)methane-diol-κN,O](sulfato-κO)copper(II) dihydrate
Abstract:
In the title compound, [Cu(SO(4))(C(10)H(9)NO(2))(2)]·2H(2)O, the Cu(II) ion is chelated by two (2-quinol-yl)methane-diol ligands and coordinated by a monodentate sulfate ligand in a distorted trigonal-bipyramidal environment, with O atoms occupying the equatorial sites and N atoms in the axial sites. The dihedral angle between the two essentially planar quinoline ring systems is 45.02 (9)°. In the crystal structure, an extensive O-H⋯O hydrogen-bonding network forms layers parallel to the ab plane.
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