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Updated: Jun 5, 2026

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Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
(μ-Piperazine-1,4-dicarbodithioato-κS,S':S'',S''')bis-[triphenyl-tin(IV)] dichloro-methane solvate
Pavel Poplaukhin1, Edward R T Tiekink
1Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, TX 78249-0698, USA.
Acta Crystallographica. Section E, Structure Reports Online
|January 5, 2011
Abstract:
The dinuclear centrosymmetric title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(8)N(2)S(4))]·CH(2)Cl(2), features a distorted cis-trigonal-bipyramidal coordination geometry for Sn based on a C(3)S(2) donor set. The dinuclear mol-ecule lies across a centre of inversion. The solvent dichloro-methane mol-ecule is disordered about a centre of inversion.

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