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Updated: Jun 5, 2026

Stable Aqueous Suspensions of Manganese Ferrite Clusters with Tunable Nanoscale Dimension and Composition
Published on: February 5, 2022
cis-Dichloridobis[2-(hydroxy-meth-yl)tetra-hydro-furan-κO,O']manganese(II)
Lucjan B Jerzykiewcz1, Józef Utko, Piotr Sobota
1Faculty of Chemistry, University of Wrocław, 14. F. Joliot Curie, 50-383 Wrocław, Poland.
Abstract:
The structure of the title compound, [MnCl(2)(C(5)H(10)O(2))(2)], was solved from low-temperature data collected at 100 (2) K. The asymmetric unit contains one half-mol-ecule with the Mn(II) ion located on a twofold axis. A distorted octa-hedral environment around the Mn atom is formed by two ether and two hydroxyl O atoms of two 2-(hydroxy-methyl)tetra-hydro-furan ligands, and by two chloride ions. The chelating tetra-hydro-furan ligands, which form five-membered rings, are cis oriented. The crystal structure is stabilized by hydrogen bonding between the coordinated OH groups and the chloride ions.
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