Related Experiment Video
Updated: Jun 5, 2026

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Zr(3)NiSb(7): a new anti-mony-enriched ZrSb(2) derivative
Abstract:
Single crystals of trizirconium nickel hepta-anti-monide were synthesized from the constituent elements by arc-melting. The compound crystallizes in a unique structure type and belongs to the family of two-layer structures. All crystallographically unique atoms (3 × Zr, 1 × Ni and 7 × Sb) are located at sites with m symmetry. The structure contains 'Zr(2)Ni(2)Sb(5)' and 'Zr(4)Sb(9)' fragments and might be described as a new ZrSb(2) derivative with a high Sb content.
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