Porphyrin-based two-dimensional covalent organic frameworks: synchronized synthetic control of macroscopic structures
Xiao Feng1, Long Chen, Yuping Dong
1Department of Materials Molecular Science, Institute for Molecular Science, National Institutes of Natural Sciences, 5-1 Higashiyama, Myodaiji, Okazaki 444-8787, Japan.
Chemical Communications (Cambridge, England)
|January 12, 2011
Abstract:
A two-dimensional porphyrin covalent organic framework is solvothermally synthesized and the macroscopic structure and pore parameters can be synthetically controlled. A remarkable and positive COF size effect on the pore parameters enables such structural control with a synchronized feature.
