Sensitivity enhancement at 594.8 nm atomic transition of Cl I for chloride detection in the reinforced concrete using LIBS

A new atomic line at 594.8 nm of neutral chlorine (Cl I) has been used as a marker to quantify the amount of chloride present in the concrete sample using Laser Induced Breakdown Spectroscopy (LIBS). Although, the relative intensity of the 594.8 nm line is 1000-fold less than that of the most commonly used intense atomic line of Cl I at 837.5 nm reported in the literature, the limit of detection of chlorine achieved with our set-up in the concrete sample using the new line is comparable with the 837.5 nm. This clearly indicates that the sensitivity of the LIBS system for detection of chlorine in concrete sample using 594.8 nm is at least 1000-fold more than the one using 837.5 nm, which can be attributed to the characteristic less self absorption. LIBS data for different concentration of chloride content in concrete sample was also carried out and a calibration curve was drawn. The excitation scheme for 594.8 nm line is also proposed in this work.