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Radical Reactivity: Steric Effects01:10

Radical Reactivity: Steric Effects

The presence of electron-donating, electron-withdrawing, or conjugating groups adjacent to a radical center, imparts electronic stabilization to the radicals. Examples of such electronically-stabilized radicals are triphenylmethyl, tetramethylpiperidine‐N‐oxide, and 2,2‐diphenyl‐1‐picrylhydrazyl. These radicals are remarkably stable and are known as persistent radicals. Some of the persistent radicals can even be isolated and purified.
Along with electronic factors, steric factors also account...
BIBO stability of continuous and discrete -time systems01:24

BIBO stability of continuous and discrete -time systems

System stability is a fundamental concept in signal processing, often assessed using convolution. For a system to be considered bounded-input bounded-output (BIBO) stable, any bounded input signal must produce a bounded output signal. A bounded input signal is one where the modulus does not exceed a certain constant at any point in time.
To determine the BIBO stability, the convolution integral is utilized when a bounded continuous-time input is applied to a Linear Time-Invariant (LTI) system.
Oscillations about an Equilibrium Position01:04

Oscillations about an Equilibrium Position

Stability is an important concept in oscillation. If an equilibrium point is stable, a slight disturbance of an object that is initially at the stable equilibrium point will cause the object to oscillate around that point. For an unstable equilibrium point, if the object is disturbed slightly, it will not return to the equilibrium point. There are three conditions for equilibrium points—stable, unstable, and half-stable. A half-stable equilibrium point is also unstable, but is named so because...
Stability01:28

Stability

The time response of a linear time-invariant (LTI) system can be divided into transient and steady-state responses. The transient response represents the system's initial reaction to a change in input and diminishes to zero over time. In contrast, the steady-state response is the behavior that persists after the transient effects have faded.
The stability of an LTI system is determined by the roots of its characteristic equation, known as poles. A system is stable if it produces a bounded...
Stability of Equilibrium Configuration01:23

Stability of Equilibrium Configuration

Understanding the stability of equilibrium configurations is a fundamental part of mechanical engineering. In any system, there are three distinct types of equilibrium: stable, neutral, and unstable.
A stable equilibrium occurs when a system tends to return to its original position when given a small displacement, and the potential energy is at its minimum. An example of a stable equilibrium is when a cantilever beam is fixed at one end and a weight is attached to the other end. If the weight...
Bioreactor Controls-II01:18

Bioreactor Controls-II

In aerobic fermentations, oxygen is vital for microbial growth and metabolite production. Since air comprises only about 20% oxygen and the gas is poorly soluble in water—just 9 ppm at 20°C—supplying sufficient oxygen becomes a critical challenge, especially in high-demand processes like yeast growth or citric acid production. Even a fully saturated broth may offer only a few seconds of oxygen availability.To address this, sterile or scrubbed air is introduced into the fermentor via a sparger...

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Related Experiment Video

Updated: Jun 5, 2026

Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System
08:19

Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System

Published on: May 9, 2021

Long-lived antibubbles: stable antibubbles through Pickering stabilization.

Albert T Poortinga1

  • 1FrieslandCampina Research, Harderwijkerstraat 6, 7418 BA Deventer, The Netherlands.

Langmuir : the ACS Journal of Surfaces and Colloids
|January 22, 2011
PubMed
Summary

Researchers created ultra-stable antibubbles, lasting tens of hours, by using colloidal particles. This breakthrough overcomes the instability issue, paving the way for advanced encapsulation applications.

Related Experiment Videos

Last Updated: Jun 5, 2026

Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System
08:19

Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System

Published on: May 9, 2021

Area of Science:

  • Physical Chemistry
  • Materials Science
  • Colloid Science

Background:

  • Antibubbles, liquid droplets with a gas shell in a liquid, offer potential for encapsulation.
  • Their practical use is limited by short lifetimes, typically minutes, due to inherent instability.

Purpose of the Study:

  • To develop a method for producing highly stable antibubbles with significantly extended lifetimes.
  • To investigate the role of colloidal particles in enhancing antibubble stability for encapsulation.

Main Methods:

  • Aqueous droplets were coated with hydrophobic colloidal particles and gelled.
  • These gelled droplets were then immersed in an aqueous colloidal suspension to form antibubbles.

Main Results:

  • The produced antibubbles exhibited remarkable stability, lasting for at least tens of hours.
  • Stability was maintained even after the gel matrix within the antibubbles melted.

Conclusions:

  • Adsorption of colloidal particles at the gas-water interface is key to achieving long-lived antibubbles.
  • This novel method enables the creation of stable antibubbles, overcoming previous limitations for applications like encapsulation.