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Related Concept Videos

Shrinkage in Concrete01:27

Shrinkage in Concrete

Shrinkage in concrete is primarily due to water loss from evaporation, hydration of cement, or carbonation, leading to a reduction in volume. The volumetric contraction results in volumetric strain in concrete. However, in practice, shrinkage is measured as linear strain, which is one-third of the volumetric strain.
When concrete is still in its plastic state, it can undergo a decrease in volume by about 1% of its absolute volume. This decrease is known as plastic shrinkage. It arises either...
Drying Shrinkage01:21

Drying Shrinkage

When hardened concrete is exposed to air with a relative humidity of less than 100 percent, it begins to lose the free water within its capillaries. As this water evaporates, the water initially adsorbed onto the calcium silicate hydrates migrates towards these now empty spaces and eventually evaporates as well. Over time, as more water leaves, the volume of the concrete decreases, a phenomenon known as drying shrinkage.
A portion of this drying shrinkage can be reversed; if the concrete is...
Polymer Classification: Architecture01:14

Polymer Classification: Architecture

Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
Carbonation Shrinkage01:24

Carbonation Shrinkage

Atmospheric CO2 penetrates the concrete's pores and, in the presence of moisture, forms carbonic acid, which then reacts with calcium hydroxide in the hydrated cement, forming calcium carbonate. This process reduces the concrete's volume and is termed carbonation shrinkage.
The concrete's permeability is slightly reduced as calcium carbonate produced during the reaction fills its pores. Furthermore, its strength is slightly enhanced as the water released during the reaction facilitates the...
Molecular Weight of Step-Growth Polymers01:08

Molecular Weight of Step-Growth Polymers

Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...

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Shrinkage of Dental Composite in Simulated Cavity Measured with Digital Image Correlation
08:45

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Published on: July 21, 2014

Do low-shrink composites reduce polymerization shrinkage effects?

D Tantbirojn1, C S Pfeifer, R R Braga

  • 1Department of Restorative Dentistry, College of Dentistry, University of Tennessee Health Science Center, Memphis, TN 38163, USA.

Journal of Dental Research
|February 2, 2011
PubMed
Summary
This summary is machine-generated.

New "low-shrink composites" do not always reduce tooth deformation. Researchers found that shrinkage stress effects depend on post-gel shrinkage and elastic modulus, not just total shrinkage. Some low-shrink materials still caused significant cuspal deflection.

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Area of Science:

  • Dental Materials Science
  • Polymer Science
  • Biomaterials Engineering

Background:

  • Advancements in polymer science have yielded
  • low-shrink composites
  • aiming to minimize polymerization shrinkage in dental restorations.

Purpose of the Study:

  • To evaluate whether reduced polymerization shrinkage in low-shrink composites translates to decreased shrinkage stress and tooth deformation in extracted human premolars.
  • To investigate the relationship between composite properties (total shrinkage, post-gel shrinkage, degree of conversion, elastic modulus) and cuspal deflection.

Main Methods:

  • Mesio-occluso-distal slot cavities were prepared in extracted human premolars (N=5) and restored with conventional or low-shrink composites.
  • Cuspal deflection was measured by digitizing coronal surfaces before and after restoration.
  • Key composite properties and microleakage were assessed to ensure adequate bonding.

Main Results:

  • All restorations induced inward cuspal deflection (9-14 microns) due to shrinkage stresses.
  • Only two low-shrink composites (Kalore and LS) significantly reduced tooth deformation.
  • Other low-shrink composites showed no significant difference in cuspal deflection compared to conventional ones, irrespective of their total shrinkage values.

Conclusions:

  • Reduced total shrinkage in low-shrink composites does not guarantee diminished shrinkage stress or tooth deformation.
  • The combination of post-gel shrinkage and elastic modulus appears to be more critical in determining cuspal deflection than total shrinkage alone.
  • Clinical implications suggest careful material selection is necessary to mitigate stress in dental restorations.