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A blue digermene (t-Bu2MeSi)2Ge=Ge(SiMet-Bu2)2
Vladimir Ya Lee1, Kiera McNeice, Yuki Ito
1Department of Chemistry, Graduated School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan. leevya@chem.tsukuba.ac.jp
Chemical Communications (Cambridge, England)
|February 3, 2011
Abstract:
A novel tetrakis(trialkylsilyl)digermene, featuring rather unusual structural and chemical properties, was synthesized by a straightforward synthetic protocol: reduction of the corresponding dichlorobis(trialkylsilyl)germane precursor with potassium graphite.
