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Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
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Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents

Published on: May 28, 2014

Design, synthesis and in vitro cytotoxicity of novel dinuclear platinum(II) complexes

Chuanzhu Gao1, Shaohua Gou, Lei Fang

  • 1Pharmaceutical Research Center and School of Chemistry and Chemical Engineering, Southeast University, Nanjing, China.

Bioorganic & Medicinal Chemistry Letters
|February 15, 2011
PubMed

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Stereoisomerism02:52

Stereoisomerism

Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...