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Tetraacenaphthoporphyrin: a π-conjugated porphyrin with efficient light-activated anticancer activity

Gaomai Yang1, Libing Liu, Qiong Yang

  • 1Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.

Chemistry, an Asian Journal
|March 9, 2011
PubMed
Abstract

No abstract available in PubMed .

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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