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Updated: Jun 3, 2026

Vapor Phase Deposition of Electroactive Poly(3,4-ethylenedioxythiophene) onto Electrospun Commodity Polymer Nanofibers
Published on: March 7, 2025
Making inert polypropylene fibers chemically responsive by combining atomic layer deposition and vapor phase chemical
Qing Peng1, Bo Gong, Gregory N Parsons
1Department of Chemical and Biomolecular Engineering, North Carolina State University, NC 27695, USA. qpeng@anl.gov
Abstract:
Uniformly grafting organic reactive molecular species, e.g. -NH₂, onto substrates that have three-dimensional complex structures and are chemically inert is challenging. The vapor phase chemical grafting of organic molecules enabled by low temperature metal oxide atomic layer deposition (ALD) is presented as a general and promising solution to functionalize inert matrices with complex morphology, such as nonwoven polypropylene mats, through the controllable self-limited molecular assembly mechanism in a combined ALD and vapor phase chemical grafting process.
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