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Published on: May 20, 2014
Spatially modulated structures in nematic colloids: Statistical thermodynamics and kinetics
A V Kleshchonok1, V Yu Reshetnyak, V A Tatarenko
1Taras Shevchenko National University of Kyiv, Physics Faculty, Ukraine. avklesh@gmail.com
Abstract:
We examine the spatial distribution of rigid-sphere-like particles in a nematic host. Using a continuum model we analyse the conditions necessary for the appearance of a modulated lamellar structure. There is a long-range effective interaction between the particles, which can lead to the formation of superstructures. In general, this interaction includes several contributions: van der Waals-type direct interaction and indirect interaction via the director field distortions. The latter depends on the temperature of the sample, the coupling energy between a colloidal particle and a nematic host, and the particle concentration. This effective interaction controls the spatial structure and the kinetic properties of the system. We obtained the analytical expression for the temperature when the system loses the stability with respect to the modulated structure formation. Typical contours of the diffuse light scattering are presented.
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