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Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Amine, alcohol and phosphine catalysts for acyl transfer reactions
Alan C Spivey1, Stellios Arseniyadis
1Department of Chemistry, South Kensington Campus, Imperial College, London, SW7 2AZ, UK. a.c.spivey@imperial.ac.uk
Abstract:
An overview of the area of organocatalytic asymmetric acyl transfer processes is presented including O- and N-acylation. The material has been ordered according to the structural class of catalyst employed rather than reaction type with the intention to draw mechanistic parallels between the manner in which the various reactions are accelerated by the catalysts and the concepts employed to control transfer of chiral information from the catalyst to the substrates.
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