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Updated: Jun 1, 2026
07:14
Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Poly[(μ(3)-4-amino-benzene-sulfonato-κN:O:O)(triphenyl-phosphine-κP)silver(I)]
Abstract:
In the title 1:1 silver 4-amino-benzene-sulfonate adduct with triphenyl-phosphine, [Ag(C(6)H(6)NO(3)S)(C(18)H(15)P)](n), the sulfon-ate -SO(3) unit bridges, through only one O atom, two phosphine-coordinated Ag atoms, forming a centrosymmetric Ag(2)O(2) rhombus. The Ag(+) cation adopts a considerably distorted a tetra-hedral coordination. In the crystal, adjacent binuclear mol-ecules are connected into a layer motif through the amino group of the anion; the layers are perpendicular to the a axis.
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