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Summary

This study details the crystal structure of C(12)H(8)Cl(4)N(2), revealing molecular symmetry and intermolecular interactions. Key findings include specific hydrogen bonds and chlorine-chlorine contacts influencing crystal packing.

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Area of Science:

Crystallography
Solid-state chemistry
Molecular structure

Background:

Understanding the three-dimensional arrangement of atoms in crystalline solids is fundamental to materials science.
Intermolecular interactions dictate crystal packing, influencing physical and chemical properties.
The specific compound C(12)H(8)Cl(4)N(2) presents an interesting case for structural analysis due to its symmetry and halogenation.

Purpose of the Study:

To elucidate the detailed crystal structure of the title compound, C(12)H(8)Cl(4)N(2).
To identify and characterize the intermolecular interactions present in the crystal lattice.
To understand the role of symmetry elements in the molecular arrangement.

Main Methods:

Single-crystal X-ray diffraction was employed to determine the atomic coordinates and unit cell parameters.
Analysis of the crystal structure involved identifying symmetry elements and measuring bond lengths and angles.
Intermolecular interactions were systematically analyzed using geometric criteria.

Main Results:

The crystal structure of C(12)H(8)Cl(4)N(2) was successfully determined.
Molecules were found to lie on crystallographic twofold axes, with the asymmetric unit comprising half a molecule.
Significant intermolecular interactions including N-H⋯N, N-H⋯Cl, C-H⋯Cl, and a notable Cl⋯Cl contact [3.4503(3) Å] were identified.

Conclusions:

The crystal structure provides a precise description of the molecular conformation and packing in C(12)H(8)Cl(4)N(2).
The identified intermolecular interactions, particularly the Cl⋯Cl contact, are crucial for stabilizing the crystal lattice.
This structural information serves as a foundation for further investigations into the compound's properties and potential applications.