The infrared dielectric tensor and axial dispersion in caesium L-malate monohydrate

Caesium hydrogen L-malate monohydrate (CsH(C(4)H(4)O(5))·H(2)O) is a novel coordination compound of L-malic acid and caesium that crystallizes into a monoclinic structure and shows promising properties for application as a piezoelectric, pyroelectric and electro-optic material. In the present work we use polarized infrared reflectivity measurements to investigate the dielectric tensor of the material in the spectral range of 40-4000 cm(-1). The use of a three-polarization technique allows us to obtain from the reflectivity data the parameters that characterize the B phonons with wavevectors varying in the plane perpendicular to the monoclinic axis. Consequently, we are able to monitor the frequency dependence of the orientation of the principal dielectric axes in this plane. Using these results we can evaluate the role of polar phonons in the low frequency dielectric response, characterize the dielectric tensor in the terahertz frequency range and describe the axial optical and dielectric dispersion over the frequency range investigated.