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Updated: May 31, 2026

Synthesis and Reaction Chemistry of Nanosize Monosodium Titanate
Published on: February 23, 2016
Di-μ-chlorido-bis[dichloridobis(methylamido-κN)bis(methylamine-κN)titanium(IV)]
Tegan Thomas1, David Pugh, Ivan P Parkin
1Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, England.
Abstract:
The title compound, [Ti(2)Cl(6)(C(2)H(6)N)(2)(C(2)H(7)N)(2)], is a binuclear octahedral complex lying about an inversion centre. There are four different chloride environments, two terminal [Ti-Cl = 2.2847 (5) and 2.3371 (5) Å] and two bridging [Ti-Cl = 2.4414 (5) and 2.6759 (5) Å], with the Ti-Cl distances being strongly influenced by both the ligand trans to the chloride and whether or not the chloride anion is bridging between the two Ti(IV) centres. The compound forms a two-dimensional network in the solid state, with weak intermolecular C-H···Cl interactions giving rise to a planar network in the (10 ̅2) plane.
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