Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Mapping reaction pathways and catalyst dynamics in electrochemical CO<sub>2</sub> reduction through <i>in situ</i> and <i>operando</i> characterisation.

Chemical communications (Cambridge, England)·2026
Same author

STEM in an SEM: Towards high-throughput imaging and analysis of metal nanoclusters.

Ultramicroscopy·2026
Same author

Direct Imaging Reveals the Atomic Mechanism of Active-Site Formation in Nanoclusters for Hydrogen Production.

Advanced materials (Deerfield Beach, Fla.)·2026
Same author

High-temperature molecular beam epitaxy of hexagonal boron nitride monolayers on carbon nanotubes.

Nanoscale·2026
Same author

Hydropyrolysis: towards fluorescence-free Raman spectroscopy analysis of internal diesel injector deposits.

The Analyst·2026
Same author

Structural and magnetic investigations of the Weyl semimetal family CeAlSi<sub>1-x</sub>Ge<sub>x</sub>.

Acta crystallographica Section B, Structural science, crystal engineering and materials·2026
Same journal

Interfacial Behavior and Adsorption Mechanisms of Sorbitol Polyether Ester Emulsifiers in D-Phase Emulsion Systems: Applications for Spontaneous Emulsification.

Langmuir : the ACS journal of surfaces and colloids·2026
Same journal

Ti<sub>3</sub> Cluster-Doped 2D Goldene Surface for Electronic and Optical Sensing of Oxygen, Nitrogen, and Hydrocarbon-Based Respiratory Biomarkers: A DFT Study.

Langmuir : the ACS journal of surfaces and colloids·2026
Same journal

Condensation of GO<i>x</i> by Restoring Global Protein Fold on Diazo-Enriched SG Surfaces: Reinstallation of FADs Restores Biocatalytic Sustainability in Quantifying Blood Glucose.

Langmuir : the ACS journal of surfaces and colloids·2026
Same journal

Correction to "Protein Encapsulated DNA Metal Nanocluster as Fluorescent Nanoprobe for Detecting Insulin".

Langmuir : the ACS journal of surfaces and colloids·2026
Same journal

Rational Design of V<sub>2</sub>O<sub>5</sub> Hierarchical Microspheres with Tunable Porosities and Primary Building Blocks for Enhanced Lithium Storage Performance.

Langmuir : the ACS journal of surfaces and colloids·2026
Same journal

Roles of Anion and Cation Doping in g-C<b><sub>3</sub></b>N<b><sub>4</sub></b> as Artificial SEI for Regulating Interfacial Zn<b><sup>2+</sup></b> Deposition in Aqueous Zinc Metal Anodes.

Langmuir : the ACS journal of surfaces and colloids·2026
See all related articles

Related Experiment Video

Updated: May 31, 2026

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
06:48

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles

Published on: June 14, 2024

Functionalized fullerenes in self-assembled monolayers.

Maria del Carmen Gimenez-Lopez1, Minna T Räisänen, Thomas W Chamberlain

  • 1School of Chemistry, University of Nottingham, NG7 2RD, United Kingdom.

Langmuir : the ACS Journal of Surfaces and Colloids
|July 13, 2011
PubMed
Summary
This summary is machine-generated.

Researchers controlled fullerene arrangement in 2D self-assembled monolayers (SAMs) by tuning anchoring groups. Thioether-fullerenes formed ordered arrays via weaker surface interactions, enabling new packing structures for nanomaterial applications.

More Related Videos

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
08:09

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates

Published on: May 9, 2014

Preparation and Characterization of C60/Graphene Hybrid Nanostructures
08:40

Preparation and Characterization of C60/Graphene Hybrid Nanostructures

Published on: May 15, 2018

Related Experiment Videos

Last Updated: May 31, 2026

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
06:48

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles

Published on: June 14, 2024

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
08:09

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates

Published on: May 9, 2014

Preparation and Characterization of C60/Graphene Hybrid Nanostructures
08:40

Preparation and Characterization of C60/Graphene Hybrid Nanostructures

Published on: May 15, 2018

Area of Science:

  • Materials Science
  • Surface Chemistry
  • Nanotechnology

Background:

  • Fullerene self-assembly into 2D monolayers is critical for nanomaterial applications.
  • Controlling fullerene arrangement requires understanding molecule-surface and intermolecular interactions.
  • Functionalization of fullerene cages with sulfur groups enables adsorption on gold substrates.

Purpose of the Study:

  • To investigate how chemical functionality influences fullerene self-assembly into 2D monolayers.
  • To explore the role of anchoring groups (thiols vs. thioethers) in fullerene SAM geometry.
  • To develop a strategy for precise control over fullerene packing arrangements on surfaces.

Main Methods:

  • Synthesis of structurally related fullerene compounds with thiol and thioether anchoring groups.
  • Scanning tunnelling microscopy (STM) to characterize the structure and order of fullerene SAMs.
  • Systematic variation of spacer groups to study their impact on fullerene row alignment and spacing.

Main Results:

  • Thioether-functionalized fullerenes form ordered 2D arrays due to weaker surface interactions and dominant intermolecular forces.
  • Thiol-functionalized fullerenes exhibit strong molecule-surface interactions, hindering long-range order.
  • Recurring linear rows of fullerenes were observed, with spacing dependent on spacer group size and shape.
  • Four novel fullerene packing arrangements were achieved through controlled chemical functionalization.

Conclusions:

  • The chemical nature of the anchoring group is paramount for achieving ordered fullerene SAMs.
  • Weakening molecule-surface interactions (e.g., using thioethers) promotes self-assembly driven by intermolecular forces.
  • Precise control over fullerene arrangement at the molecular level is achievable via tailored functionalization.
  • This strategy advances the development of practical applications for fullerene-based nanomaterials.