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Updated: May 31, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
2-[1-(3-Amino-phenyl-imino)-eth-yl]phenol
Abstract:
The title compound, C(14)H(14)N(2)O, exists as the enol-imine tautomer. A strong intra-molecular hydrogen bond between O and N atoms forms a six-membered ring with an S(6) graph-set motif, which is approximately coplanar with the phenol ring, the inter-planar angle being 3.4 (3)°. In the crystal, inter-molecular C-H⋯O hydrogen bonds and N-H⋯π inter-actions link the mol-ecules into infinite chains along [100].
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