Related Experiment Video
Updated: May 30, 2026

Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach
Published on: June 10, 2021
Luminescent bichromophoric spiroindolones--synthesis and electronic properties
Jan Schönhaber1, Thomas J J Müller
1Lehrstuhl für Organische Chemie, Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Düsseldorf, Germany.
Abstract:
Novel bichromophoric spirocyclic indolones have been synthesized by an insertion-coupling-isomerization-Diels-Alder domino reaction. The emission colors are strongly affected by the substituents: N-Boc leads to intense blue fluorescence, N-dansyl causes turquoise emission, whereas a 1-anthryl substituent on the butadiene results in yellow luminescence. The latter behavior is rationalized by TDDFT computations as a result of significant geometrical changes.
Related Concept Videos
Photoluminescence: Applications
Photoluminescence: Fluorescence and Phosphorescence
A pair of electrons in a...
Variables Affecting Phosphorescence and Fluorescence
![Solid-phase Synthesis of [4.4] Spirocyclic Oximes](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F58508.jpg&w=3840&q=50)
