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Updated: May 30, 2026
07:14
Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
A mesoporous metal-organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24]
Yong Yan1, Sihai Yang, Alexander J Blake
1School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK.
Chemical Communications (Cambridge, England)
|August 11, 2011
Abstract:
The mesoporous framework [Cu(3)(L)(H(2)O)(3)]·(DMF)(35)·(H(2)O)(35) (NOTT-119) shows on desolvation a BET surface area of 4118(200) m(2) g(-1), a pore volume of 2.35 cm(3) g(-1), a total H(2) uptake of 101 mg g(-1) at 60 bar, 77 K and a total CH(4) uptake of 327 mg g(-1) at 80 bar, 298 K.
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